منابع مشابه
l-Alanine hydrochloride monohydrate
Colorless crystals of l-alanine hydrochloride monohydrate, C(3)H(8)NO(2) (+)·Cl(-)·H(2)O, were obtained from a powder sample that had been left standing in a refrigerator for a few years. The structure displays several inter-molecular hydrogen bonds: the hydroxyl O atom is involved in a single hydrogen bond to the chloride anion, while the ammonium group forms one hydrogen bond to the chloride ...
متن کاملl-Alanine methyl ester hydrochloride monohydrate
The enanti-opure title compound, C(4)H(10)NO(2) (+)·Cl(-)·H(2)O, forms a two-dimensional network by inter-molecular hydrogen bonding parallel to (010). Non-merohedral twinning with a twofold rotation about the reciprocal c* axis as twin operation was taken into account during intensity integration and structure refinement. This twinning leads to alternative orientations of the stacked hydrogen-...
متن کاملl-Leucinium fluoride monohydrate
The asymmetric unit of the title hydrated salt, C(6)H(14)NO(2) (+)·F(-)·H(2)O, contains a discrete cation with a protonated amino group, a halide anion and one water mol-ecule. The crystal structure is composed of double layers parallel to (010) held together by N-H⋯O, N-H⋯F, O-H⋯F and C-H⋯F hydrogen bonds, forming a two-dimensional network, and stacked along the c axis, viz. hydro-philic layer...
متن کاملCatalytic Stereoinversion of L-Alanine to Deuterated D-Alanine.
A combination of an achiral pyridoxal analogue and a chiral base has been developed for catalytic deuteration of L-alanine with inversion of stereochemistry to give deuterated D-alanine under mild conditions (neutral pD and 25 °C) without the use of any protecting groups. This system can also be used for catalytic deuteration of D-alanine with retention of stereochemistry to give deuterated D-a...
متن کاملAffinity labeling of alanine aminotransferase by 3-chloro-L-alanine.
The pyridoxal form of alanine aminotransferase from pig heart catalyzes the a,/? elimination reaction with 3chloro-L-alanine as the substrate to form equimolar amounts of pyruvate, ammonia, and chloride. The maximum rate of the a,/3 elimination reaction was 2.5 pmol/min/mg at pH 7.0 (25”(Z), approximately 0.5% that of the transamination reaction between L-alanine and 2-oxoglutarate. Time-depend...
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ژورنال
عنوان ژورنال: Acta Crystallographica Section E Structure Reports Online
سال: 2008
ISSN: 1600-5368
DOI: 10.1107/s1600536808008751